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ChemInform Abstract: A New Synthetic Approach to α-Aminophosphonic Acids: Synthesis and NMR Characterization.

✍ Scribed by Kolio Troev; Sheldon Cremer; Gerhard Haegele


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
31
Category
Article
ISSN
0931-7597

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A new synthetic approach to α-aminophosp
✍ Kolio Troev; Sheldon Cremer; Gerhard Hägele 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 192 KB 👁 1 views

In this article, a new synthetic approach to a 1,4,2-oxazaphosphorinane, and to ␣-ethyl-␣-N-(hydroxyethylamino)methyl phosphonicacid and their sodium salts is described. The title compounds were characterized by NMR and FAB spectroscopy.

ChemInform Abstract: Synthesis of α-Subs
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Synthesis of α-Substituted α-Aminophosphinic and α-Aminophosphonic Acids. -The reaction of ketoximes (I) with hypophosphorous acid affords previously unknown phosphinic acids (II), which are smoothly oxidized into the corresponding phosphonic acids (III). -(OSIPOVA, T. I.;