ChemInform Abstract: A New Stereocontrolled Access to Angularly Disubstituted cis-Decalins via Tandem Radical Ring Expansion and Cyclization.
β Scribed by H. NEMOTO; M. SHIRAKI; N. YAMADA; N. RAKU; K. FUKUMOTO
- Book ID
- 112041018
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The substituted dioxacyclic compounds (III) and (XI) are synthesized via the inter-and intramolecular "pincer" Diels-Alder reaction. The first ring-opening reaction of these compounds is significantly faster than the second. Treatment of tetracycle (IV) with BuLi at higher temperatures provides the
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