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ChemInform Abstract: A New Route to 1,1-Difluoroolefins.

✍ Scribed by F. TELLIER; M. BAUDRY; R. SAUVETRE

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

The transformation of bromides (I) (prepared via a previously reported reaction of aldehydes/ketones with difluorovinyllithium) to (III) and ( VI) represents a general and highly regioselective methodology for the introduction of a difluorovinylic group. The silylated products (VI) are useful precursors of more complex fluorinated molecules. -(TELLIER, F.;

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