A new practical 10 step synthesis of (1S,2R)-2-acetyl-1 -methylcyclobtRaneacetic acid 15 is reported, which has as a key step a flaodium catalyzed intramolecular carbonoid cyclizstion of the ct-diazo-13-ketosuffone 5, readily available from (+)-cittonellol 2. Since 15 has already been conveRed into
โฆ LIBER โฆ
ChemInform Abstract: A New Practical Synthesis of (+)-Grandisol from (+)-Citronellol Using an Intramolecular Carbenoid Cyclization.
โ Scribed by H. J. MONTEIRO; J. ZUKERMAN-SCHPECTOR
- Book ID
- 112034489
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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