ChemInform Abstract: A New Method for the Synthesis of Allyl Arylselenides via the Reaction of the Zinc Allyl Selenoates with Diaryliodonium Salts.

✍ Scribed by X. HUANG; X.-H. XU

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 28 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199824148

✦ Synopsis

1998 organo-selenium compounds, isocyclic C derivatives organo-selenium compounds, isocyclic C derivatives S 0134 24 -148 A New Method for the Synthesis of Allyl Arylselenides via the Reaction of the Zinc Allyl Selenoates with Diaryliodonium Salts. -The present method provides a new one-pot synthesis of allyl arylselenides (III) in high yields. Experimental results show that the reaction of zinc allyl selenoate with diaryliodonium salts (II) proceeds most efficiently in THF-HMPA (2:1). -(HUANG, X.;