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ChemInform Abstract: A Mixed Fullerene-Ferrocene Thermotropic Liquid Crystal: Synthesis, Liquid-Crystalline Properties, Supramolecular Organization and Photoinduced Electron Transfer.

✍ Scribed by Michael Even; Benoit Heinrich; Daniel Guillon; Dirk M. Guldi; Maurizio Prato; Robert Deschenaux


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
33
Category
Article
ISSN
0931-7597

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A Mixed Fullerene–Ferrocene Thermotropic
✍ Michaël Even; Benoit Heinrich; Daniel Guillon; Dirk M. Guldi; Maurizio Prato; Ro 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 235 KB 👁 1 views

Grafting of a ferrocene-containing liquid-crystalline malonate derivative to C 60 led to the mixed fullerene ± ferrocene material 1 which gave rise to a smectic A phase. Cholesterol was used as liquid-crystalline promoter. X-ray diffraction experiments and volumetric measurements indicated that 1 is