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ChemInform Abstract: A Mild Palladium Catalyzed N-Allylation of Amino Acids and Peptides.

✍ Scribed by F. L. ZUMPE; U. KAZMAIER

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Mild Palladium Catalyzed N-Allylation of Amino Acids and Peptides. -In connection with ring-closing metathesis reactions of N-allylated amino acids, a mild method for the conversion of N-amino acid esters to the corresponding N-allylated derivatives by Pd-catalyzed reaction with allyl ethyl carbonate is described. The reaction proceeds without epimerization.

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