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ChemInform Abstract: A Mild and Convenient Oxidation of H-Phosphinic Acids.

โœ Scribed by L. Berlicki; A. Mucha; P. Kafarski


Publisher
John Wiley and Sons
Year
2008
Weight
31 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Convenient Access
โœ E. SOULIER; J.-C. CLEMENT; J.-J. YAOUANC; H. DES ABBAYES ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB

Reduction of phosphinic acids (I) with phenylsilane or of the corresponding diacids (V) with LiAlH 4 provides phosphines (II) or diphosphines (III) via their acid chlorides. They may be used in Michael additions with the activated alkene (V) or in most cases as stable borane adducts such as (VII) an