𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: A High-Valent Iron(IV) Oxo Porphyrin Cation Radical Complex in Olefin Epoxidation Reactions.

✍ Scribed by Yoon Jung Lee; Cheal Kim; Youngah Kim; So-Yeop Han; Wonwoo Nam

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: Epoxidation of Olef
ChemInform Abstract: Epoxidation of Olefins by a Water-Soluble Iron(III) Porphyrin Complex and Hydroperoxides in Aqueous Solution.
✍ S. J. YANG; H. J. LEE; W. NAM 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 3 views

Epoxidation of Olefins by a Water-Soluble Iron(III) Porphyrin Complex and Hydroperoxides in Aqueous Solution. -Based on the results of the title reaction of (I) with different olefins (II)-(IV) and comparison with other oxidants the possible mechanism is discussed. Preliminary studies concerning ste

Mechanistic Insights into the Reversible
Mechanistic Insights into the Reversible Formation of Iodosylarene–Iron Porphyrin Complexes in the Reactions of Oxoiron(IV) Porphyrin π-Cation Radicals and Iodoarenes: Equilibrium, Epoxidizing Intermediate, and Oxygen Exchange
✍ Woon Ju Song; Ying Ji Sun; Sun Kyung Choi; Wonwoo Nam 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 319 KB 👁 2 views

## Abstract We have shown previously that iodosylbenzene–iron(III) porphyrin intermediates (2) are generated in the reactions of oxoiron(IV) porphyrin π‐cation radicals (1) and iodobenzene (PhI), that 1 and 2 are at equilibrium in the presence of PhI, and that the epoxidation of olefins by 2 afford