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ChemInform Abstract: A General Approach to High-Yielding Asymmetric Synthesis of Chiral 3-Alkyl-4-nitromethylchromans via Cascade Barbas—Michael and Acetalization Reactions.

✍ Scribed by Dhevalapally B. Ramachary; M. Shiva Prasad; R. Madhavachary


Publisher
John Wiley and Sons
Year
2011
Weight
49 KB
Volume
42
Category
Article
ISSN
0931-7597

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Asymmetric Induction via an Intramolecular Haloetherification Reaction of Chiral Ene Acetals: A Novel Approach to Optically Active 1,4-and 1, 5-Diols. -A new asymmetric synthesis of chiral 1,4-(XVI) and 1,5-diols (XVIII) is developed based on remote asymmetric induction of 2 stereogenic centers int