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ChemInform Abstract: A General Approach to Enantiomeric γ-Aminophosphonic Acids Using Chiral Sulfinimine Methodology.

✍ Scribed by Piotr Lyzwa; Marian Mikolajczyk


Publisher
John Wiley and Sons
Year
2011
Weight
42 KB
Volume
42
Category
Article
ISSN
0931-7597

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A general approach to enantiomeric γ-ami
✍ Piotr Łyżwa; Marian Mikołajczyk 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 308 KB

## Abstract A new approach to asymmetric synthesis of γ‐aminophosphonic acids is described. It involves the diastereoselective addition of various carbon and phosphorus nucleophiles to enantiopure (+)‐(__S__)‐__N__‐[(3‐diethoxyphosphoryl)propylidene]‐p‐toluenesulfinamide and subsequent acid hydroly