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ChemInform Abstract: A Further Synthesis of an Analogue of the Antifungal/Antiherbivore Lipid from Avocado.

✍ Scribed by R. M. CARMAN; T. KAROLI

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199907256

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✦ Synopsis

An additional approach to the saturated racemic derivative (X) of the avocado diene "persin" is developed via the key compound (V). This well known aldehyde is oxidized utilizing the simpler periodinane oxidation with modified work-up. Removal of the protecting group in (VIII) is somewhat problematic because of the lability of the deprotected product under acidic conditions. -(CARMAN, R. M.; KAROLI, T.; Aust.

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