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ChemInform Abstract: A Functional Mimic of Natural Peroxidases: Synthesis and Catalytic Activity of a Non-Heme Iron/Peptide Hydroperoxide Complex.

✍ Scribed by C. T. CHOMA; E. P. SCHUDDE; R. M. KELLOGG; G. T. ROBILLARD; B. L. FERINGA

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Functional Mimic of Natural Peroxidases: Synthesis and Catalytic Activity of a Non-Heme Iron/Peptide Hydroperoxide Complex.

-Site-selective attachment of unprotected peptides to a non-heme iron complex is achieved by displacing two halides on the catalyst by peptide caesium thiolates. The oxidation activity with hydrogen peroxide of the dipeptide-catalyst complex in water is retained, and shows similarities with oxidation mechanisms observed for natural oxidizing enzymes. -(CHOMA, C. T.; SCHUDDE, E.

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