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ChemInform Abstract: A Formal Synthesis of Crinipellin B Based on the Arene—Alkene meta-Photocycloaddition Reaction.

✍ Scribed by P. A. WENDER; T. M. DORE


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
30
Category
Article
ISSN
0931-7597

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Synthesis of Polycyclic Compounds Based on the Reaction of 6,6-Dimethylfulvene with Carbenes. -Reaction of dimethylfulvene (I) with ethoxycarbonylcarbene, in situ obtained by copper-catalyzed destruction of ethyl diazoacetate (II), proceeds at the endocyclic double bond with cyclopropane ring forma