ChemInform Abstract: A Ferromagnetic Carbodiimide: Cr2(NCN)3.

✍ Scribed by Xiaojuan Tang; Hongping Xiang; Xiaohui Liu; Manfred Speldrich; Richard Dronskowski

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 18 KB
• Volume: 41
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201040016

✦ Synopsis

Abstract

The title compound, the first transition‐metal(III) carbodiimide with a 3d^3^ configuration is prepared from a mixture of CrCl~3~ and ZnNCN using LiCl/KCl as a flux (550 °C, 2 d).