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ChemInform Abstract: A Facile Synthetic Method for the Preparation of Benzylic Manganese Halides Using Highly Active Manganese and Their Coupling Reactions.

✍ Scribed by S.-H. KIM; R. D. RIEKE

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199909204

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✦ Synopsis

A Facile Synthetic Method for the Preparation of Benzylic Manganese Halides Using Highly Active Manganese and Their Coupling Reactions.

-Treatment of different benzyl halides with highly active Mn leads to benzylic manganese halides which easily react with several electrophiles to afford the corresponding cross-coupling products. In contrast, the reaction of the bromide (VII) gives the homo-coupling product (VIII). -(KIM, S.-H.;

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