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ChemInform Abstract: A Facile and Efficient Stereoselective Synthesis of Highly Functionalized Trisubstituted Alkene Derivatives of Ferrocenealdehyde.

✍ Scribed by Ponnusamy Shanmugam; Vadivel Vaithiyanathan; Baby Viswambharan; Suchithra Madhavan

Publisher
John Wiley and Sons
Year
2008
Weight
36 KB
Volume
39
Category
Article
ISSN
0931-7597

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Typical example: (3-Formylpropyl)benzoate 2c (19.2 g, 0.1 mol) was mixed with methyl acrylate 3 (13 g; 14 mL; 0.15 mol). After addition of DABCO (1.6 g, 0.015 mol) the resulting homogeneous mixture was allowed to stand at room temperature until 2c was no longer detectable (cu. 7 days). The remaining