ChemInform Abstract: A Disilanyl Dianion and a Silyl Dianion from a Stable Silylene.
β Scribed by Robert West; Thomas A. Schmedake; Michael Haaf; James Becker; Thomas Mueller
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 28 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Metal reduction of the polycycle **2** yields a surprisingly stable dianion with intact molecular framework. This conclusion can be drawn from reoxidation experiments and from an analysis of the ^1^HβNMR. spectrum. The excess charge turns out to be distributed over both the Οβ and Οβfra
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