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ChemInform Abstract: A Convenient Synthesis of Unsymmetrical, Substituted γ-Pyrones from Meldrum′s Acid.

✍ Scribed by F. J. ZAWACKI; M. T. CRIMMINS

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Convenient Synthesis of Unsymmetrical, Substituted γ-Pyrones from Meldrum's Acid.

-Mono-and disubstituted γ-pyrones, versatile polyketide equivalents, are readily available without strong base or low reaction temperature. -(ZAWACKI, F.

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Facile Stereoselective Synthesis of γ-Substituted γ-Amino Acids from the Corresponding α-Amino Acids. -The mild and short procedure presented is compatible with common side-chain protecting groups, sensitive functionalities and preserves the chirality of the starting α-amino acid.