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ChemInform Abstract: A Convenient Synthesis of Dialkyl [[2-(Bromomethyl)aziridin-1-yl]methyl]phosphonates, New Heterocyclic β-Azaphosphonates.

✍ Scribed by C. STEVENS; A. VERBEKE; N. DE KIMPE

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Convenient Synthesis of Dialkyl aziridin-1yl]methyl]phosphonates, New Heterocyclic β-Azaphosphonates.

-Reaction of readily prepared triazine (III) with dialkyl phosphites followed by bromination and final ring closure with NaBH 4 in methanol provides

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Synthesis and Properties of N-(1-Hydroxyimino-2-methyl-1-(2pyridyl) prop-2-yl)hydroxylamine and Therefrom Derived Heterocyclic Derivatives. -The title compound (V), a new representative of the α-hydroxylamino-oxime series, is synthesized starting from 2-cyanopyridine (I) and transformed into various