ChemInform Abstract: A Convenient Method for the Synthesis and Some Transformations of Bis(diethoxyphosphoryl)fluoromethane Lithium Salt.

✍ Scribed by B. I. MARTYNOV; V. B. SOKOLOV; A. YU. AKSINENKO; T. V. GOREVA; T. A. EPISHINA; A. N. PUSHIN

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 31 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199908179

✦ Synopsis

A Convenient Method for the Synthesis and Some Transformations of Bis(diethoxyphosphoryl)fluoromethane Lithium Salt. -Reaction of (diethoxyphosphoryl)fluoro(chloro)methane (I) with butyllithium represents a convenient synthetic approach to the title bisphosphorylfluoromethane lithium salt. The lithium intermediate is trapped by reactions with water, propanal or dimethyl sulfate to furnish compounds (II), (IV), or (VI)