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ChemInform Abstract: A Concise Enantioselective Pathway to Carbocyclic Nucleoside: Asymmetric Synthesis of Carbocyclic Moiety of Carbovir.

✍ Scribed by S. TANIMORI; M. TSUBOTA; M. HE; M. NAKAYAMA

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Concise Enantioselective Pathway to Carbocyclic Nucleoside: Asymmetric Synthesis of Carbocyclic Moiety of Carbovir.

-An enantioselective synthesis of cyclopentenol (VIII), an advanced intermediate for the preparation of carbovir, involving the Rh(II)-catalyzed intramolecular cyclopropanation of a chiral Ξ±-diazo-. beta.-ketoester as the key step is given.

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ChemInform Abstract: Stereoselective Syn
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✍ Mukund K. Gurjar; Kundarapu Maheshwar πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 1 views

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