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ChemInform Abstract: A Brand-New Pd-Mediated Generation of Benzyne and Its [2 + 2 + 2] Cycloaddition: δ-Carbon Elimination and Concomitant Decarboxylation.

✍ Scribed by Hoo Sook Kim; Saravanan Gowrisankar; Eun Sun Kim; Jae Nyoung Kim

Book ID
102022208
Publisher
John Wiley and Sons
Year
2009
Weight
30 KB
Volume
40
Category
Article
ISSN
0931-7597

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A brand-new Pd-mediated generation of benzyne and its [2+2+2] cycloaddition: δ-carbon elimination and concomitant decarboxylation
✍ Hoo Sook Kim; Saravanan Gowrisankar; Eun Sun Kim; Jae Nyoung Kim 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 169 KB

We found a brand-new method for the generation of aryne from methyl 2-bromobenzoates via the Pd-mediated concomitant d-carbon elimination and decarboxylation. The generated arynes underwent Pd-mediated [2+2+2] cycloaddition to give triphenylenes.