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ChemInform Abstract: 7,14-Dichloro[1.1]metacyclophane: A Highly Strained Aromatic Intermediate.

✍ Scribed by M. J. VAN EIS; F. J. J. DE KANTER; W. H. DE WOLF; F. BICKELHAUPT

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

10 -106

7,14-Dichloro[1.1]metacyclophane: A Highly Strained Aromatic Intermediate.

-The attempted synthesis of the dichloro derivative (IV) by elimination reaction of the hexachlorobispropellane (I) affords the 2 compounds (II) and (III). The formation of both compounds is explained by a mechanism with the title compound (IV) as the intermediate. -(VAN EIS, M.

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