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ChemInform Abstract: 6-Endo-Trig Radical Cyclizations: Synthetic Approaches to the A-B Ring of (.+-.)-Forskolin.

โœ Scribed by C. ANIES; L. BILLOT; J.-Y. LALLEMAND; A. PANCRAZI


Book ID
112025439
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: 5-Endo-trig Radical
โœ Stephane Bogen; Mihaela Gulea; Louis Fensterbank; Max Malacria ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 1 views

5-Endo-trig Radical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes. -The title ethers (I), (V) and (VIII) undergo a radical-induced 5-exo-dig cyclization-diastereoselective 1,5-hydrogen transfer-5-endo-trig