Reactions of the in situ generated thiazoles 2 with aryl and alkyl isothiocyanates appear to be totally regioselective and give the unexpected 5-(phenylthio)imidazolium-4-thiolates 3. Such rapid interconversion of mesoionic compounds is explained by a 1,3-dipolar addition to the CโซืกโฌN bond of the he
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ChemInform Abstract: 5-Aminothiazolium Salts as Potential Cyclic Azomethine Ylides: Base-Induced Cycloaddition Reactions with Aryl, Alkyl, and Benzoyl Isothiocyanates.
โ Scribed by Adile Touimi Benjelloun; Georges Morel; Evelyne Marchand
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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ChemInform Abstract: 5-Aminothiazolium S
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A series of 5-aminothiazolium chlorides (1) bearing tethered cycloadducts are deduced from their spectroscopic NMR properties and unequivocally established by an X-ray benzene ring on N-3, C-4 or the exocyclic nitrogen atom are prepared by a three-component methodology and subjected diffraction anal