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ChemInform Abstract: 5-Aminothiazolium Salts as Potential Cyclic Azomethine Ylides: Base-Induced Cycloaddition Reactions with Aryl, Alkyl, and Benzoyl Isothiocyanates.

โœ Scribed by Adile Touimi Benjelloun; Georges Morel; Evelyne Marchand


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
31
Category
Article
ISSN
0931-7597

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5-aminothiazolium salts as potential cyc
โœ Adile Touimi Benjelloun; Georges Morel; Evelyne Marchand ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 220 KB ๐Ÿ‘ 1 views

Reactions of the in situ generated thiazoles 2 with aryl and alkyl isothiocyanates appear to be totally regioselective and give the unexpected 5-(phenylthio)imidazolium-4-thiolates 3. Such rapid interconversion of mesoionic compounds is explained by a 1,3-dipolar addition to the Cโ€ซืกโ€ฌN bond of the he

5-Aminothiazolium Salts as Potential Cyc
โœ Georges Morel; Evelyne Marchand; Adile Touimi Benjelloun; Sourisak Sinbandhit; O ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 334 KB

A series of 5-aminothiazolium chlorides (1) bearing tethered cycloadducts are deduced from their spectroscopic NMR properties and unequivocally established by an X-ray benzene ring on N-3, C-4 or the exocyclic nitrogen atom are prepared by a three-component methodology and subjected diffraction anal