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ChemInform Abstract: 4 + 3 and Fluorinative 4 + 3 Cycloadditions of Alkyne 1,4-Diether Dicobalt Complexes.

✍ Scribed by Manoj M. Patel; James R. Green

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

1999 cycloaddition reactions cycloaddition reactions O 0070 26 -048 4 + 3 and Fluorinative 4 + 3 Cycloadditions of Alkyne 1,4-Diether Dicobalt Complexes. -BF 3 β€’OEt 2 mediated cycloaddition of alkynyl diether dicobalt complexes with stannylsilanes provides cycloheptyne cobalt complexes [cf. (III), (VIII)] or fluorocycloheptyne cobalt complexes [cf. (IV), (VI), (X)] depending on the reaction time as well as the dilution conditions.

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