ChemInform Abstract: 3,6-Dihydropyridines from 6-endo Radical Cyclization onto Nitrogen in β-Allenyl Ketoximebenzoates.
✍ Scribed by Michael Depature; Didier Siri; Jacques Grimaldi; Jacques Hatem; Robert Faure
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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Unexpected Stereoselective 6-exo versus 7-endo Aryl Radical Cyclization Controlled by Positional Isomers in a Chiral Octahydro-1,3-benzoxazine Moiety. -Radical cyclization of benzoxazine (I) results in formation of two major cyclization diastereomers (II) and (III) via a 6-exo-trig process. Surpris