✦ LIBER ✦
ChemInform Abstract: (2,7-Dimethyl-1,8-biphenylenedioxy)bis(dimethylaluminum) as a Bidentate Lewis Acid: Its Reactivity and Selectivity in Organic Synthesis.
✍ Scribed by T. OOI; M. TAKAHASHI; K. MARUOKA
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
1997 reduction, hydrogenation reduction, hydrogenation O 0220 10 -058
(2,7-Dimethyl-1,8-biphenylenedioxy)bis(dimethylaluminum) as a Bidentate Lewis Acid: Its Reactivity and Selectivity in Organic Synthesis.
-The high double-coordination ability of the title bis(organoaluminum) reagent strongly enhances the reactivity of carbonyl substrates. Several examples demonstrate that in some reductions, aldol and addition reactions the title reagent is in high preference to a monodentate organoaluminum reagent. -(OOI, T.;