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ChemInform Abstract: 2,2′,4,4′,6-Penta-tert-butylbenzil: An Unexpected Product in the Attempted Coupling of Tri-tert-butylbenzoyl Chloride with Magnesium—Magnesium Iodide.

✍ Scribed by J. FREY; Z. RAPPOPORT


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


An Unexpected Product in the Attempted Coupling of Tri-tert-butylbenzoyl Chloride with Magnesium-Magnesium Iodide.

-In the synthesis of the desired compound (IV) (yield given in g) an unusual loss of tert-butyl groups is observed to give products (V). -(FREY,