𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: 2,2′-Bipyridinium Chlorochromate/m-Chloroperbenzoic Acid-Mediated Cleavage of Cyclic Acetals to Hydroxyesters.

✍ Scribed by F. A. LUZZIO; R. A. BOBB

Book ID
101849539
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis

1997 cleavage reactions, decomposition reactions, pyrolysis cleavage reactions, decomposition reactions, pyrolysis O 0100 26 -050 2,2'-Bipyridinium Chlorochromate/m-Chloroperbenzoic Acid-Mediated Cleavage of Cyclic Acetals to Hydroxyesters.

-A reagent system composed of MCPBA and 2,2'-bipyridinium chlorochromate effectively cleaves a variety of benzylidene acetals to yield the corresponding hydroxy esters and may be used for the preparation of protected glycosyl donors for polysaccharide synthesis. -(LUZZIO, F.

📜 SIMILAR VOLUMES

2,2′-Bipyridinium chlorochromate/m-chlor
2,2′-Bipyridinium chlorochromate/m-chloroperbenzoic acid-mediated cleavage of cyclic acetals to hydroxyesters
✍ Frederick A. Luzzio; Rhiana A. Bobb 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 166 KB

Benzylidene acetals are cleaved to hydroxyesters by means of a reagent system composed of 2,2'-bipyridinium chlorochromate (BPCC) and m-chloroperbenzoic acid. Oxidative cleavage of a 4,6.O-benzylideae glucose derivative affords a 6-O-beazoyl derivative.

ChemInform Abstract: Deracemization of a
ChemInform Abstract: Deracemization of anti-1,2-Diols Leading to trans-Epoxides via Oxazaborolidine-Mediated Enantiomer-Differentiating Ring-Cleavage of Acetal Derivatives.
✍ Toshiro Harada; Tomohito Nakamura; Motoharu Kinugasa; Akira Oku 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

Deracemization of anti-1,2-Diols Leading to trans-Epoxides via Oxazaborolidine-Mediated Enantiomer-Differentiating Ring-Cleavage of Acetal Derivatives. -An enantioconvergent transformation of racemic anti-1,2-diols (I) and (V) to enantiomerically enriched trans epoxides (IV) and (VII), resp., is rea

ChemInform Abstract: Chiral Oxazaborolid
ChemInform Abstract: Chiral Oxazaborolidinone-Mediated Enantioselective Ring-Cleavage Reaction of a Mixture of Diastereomeric 1,3-Dioxolane Acetals: Application to Asymmetric Desymmetrization of meso-1,2-Diols.
✍ Toshiro Harada; Hideki Yamanaka; Akira Oku 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v