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ChemInform Abstract: 2-Cyano-isopropyl Radical Addition to Alkynes.

โœ Scribed by P. C. MONTEVECCHI; M. L. NAVACCHIA; P. SPAGNOLO


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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Thiol radical addition to alkynes. Sulfa
โœ Daniela Melandri; Pier Carlo Montevecchi; Maria Luisa Navacchia ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 741 KB

2-(Toluenestdfanyl)-1 and 2-(benzenesuifanyl)-phenylac~ 10 reacted with benzenethiol and toluenethiol, respectively, in the presence of AIBN at 84 and 154 ยฐC to give prodm:ts deriving from vinyl radicals 2 which undergo hydrogen abstraction reaction and 5-orgm and 5-.exo eyclization onto both the ad