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ChemInform Abstract: (1R,3R)-2-Methylene-1,3-dithiolane 1,3-Dioxide: A Highly Reactive and Highly Selective Chiral Ketene Equivalent.

โœ Scribed by V. K. AGGARWAL; J. DRABOWICZ; R. S. GRAINGER; Z. GUELTEKIN; M. LIGHTOWLER; P. L. SPARGO


Book ID
112023784
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
26
Category
Article
ISSN
0931-7597

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Synthesis and Diels-Alder reactions of 2
โœ William R. Roush; Amy P. Essenfeld; Joseph S. Warmus; Bradley B. Brown ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 284 KB

Chiral dienophiles l-3 undergo highly exo and diasfereoface selective Die/s-Alder reactions. The Die/s-Alder reactions of 3 are also highly exo selective under Lewis acid catalyzed conditions. In connection with an ongoing effort in the natural products arena we required a highly diastereoselective