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ChemInform Abstract: 1,6-Anhydro-2,3-di-O-benzyl-5C- [(R)-ethoxycarbonyl(hydroxy)methyl]-β-L-altrofuranose.

✍ Scribed by Claude Taillefumier; Christophe Charron; Yves Chapleur; Andre Aubry


Publisher
John Wiley and Sons
Year
2001
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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Abstract

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Synthesis and Glycosidic Coupling Reaction of Substituted 2,6-Dioxabicyclo[3.1.1]heptanes: 1,3-Anhydro-2-azido-4,6-di-O-benzyl-2deoxy-β-D-mannopyranose. -The title sugar (VII) is synthesized via the key intermediate (VI) starting from glucopyranoside (I). Anhydrosugar (VII) is quite reactive: ring-