ChemInform Abstract: (15-Crown-5)caesium Dicopper(I) Triiodide, (15-Crown-5)potassium Dicopper(I) Triiodide and (15-Crown-5)rubidium Dicopper(I) Triiodide.

✍ Scribed by A. K. NURTAEVA; E. M. HOLT

• Book ID: 101869313
• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 35 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199833011

✦ Synopsis

1998 structure structure (solids and liquids) D 2000 33 -011 (15-Crown-5)caesium Dicopper(I) Triiodide, (15-Crown-5)potassium Dicopper(I) Triiodide and (15-Crown-5)rubidium Dicopper(I) Triiodide. -The isostructural title compounds (III) crystallize in the monoclinic system, space group C2/c, Z = 8. The structure contains a polymeric Cu 2 I 3 - moiety, catena-poly[ [Cu I -(µ 2 -I)-Cu I ] -(µ 3 -I) 2 ], composed of a series of opposite edge-sharing Cu 2 I 2 rhombs, with alternate units bridged by an additional iodine atom with up-up-down-down pattern. -(NURTAEVA, A.