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ChemInform Abstract: 1,4-Dicarbonyl-2,5-cyclohexadiene.

✍ Scribed by R. MARQUARDT; W. SANDER; T. LAUE; H. HOPF

Book ID
112023714
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
26
Category
Article
ISSN
0931-7597

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1,4-dicarbonyl-2,5-cyclohexadiene
1,4-dicarbonyl-2,5-cyclohexadiene
✍ Marquardt, Ralph ;Sander, Wolfram ;Laue, Thomas ;Hopf, Henning πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 455 KB

## Abstract The mechanism of the photolysis of [2.2]paracyclophane‐1,10‐dione (9) was investigated in solution and in argon matrices. The first step of the photolysis involves α‐cleavage of the cyclophane yielding a diradical 11 which could be trapped by ethanol. In argon at 10 K the diradical rapi