ChemInform Abstract: 1,3-Dipolar Cycloadditions of Photoinduced Carbonyl Ylides. Part 2. Photoreactions of α,β-Unsaturated γ,δ-Epoxy Dinitriles and Ethyl Vinyl Ether.

ChemInform Abstract: 1,3-Dipolar Cycload

ChemInform Abstract: 1,3-Dipolar Cycloadditions of Photoinduced Carbonyl Ylides. Part 3. Photoreactions of α,β-Unsaturated γ,δ-Epoxy Dinitrile, α-Cyano Ester, and Diester with Various Dipolarophiles.

✍ Masashi Kotera; Keitaro Ishii; Masaru Hiraga; Masanori Sakamoto 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

Part 3. Photoreactions of α,β-Unsaturated γ,δ-Epoxy Dinitrile, α-Cyano Ester, and Diester with Various Dipolarophiles. -Photolysis of the dinitrile (I) generates a carbonyl ylide which undergoes 1,3-dipolar cycloaddition with enol ethers [cf. (II)] to give cycloadducts (III) and (IV) in low yields.