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ChemInform Abstract: 1,3-Dipolar Cycloadditions of a Chiral Oxazolidinone (I) with Nitrones and Nitrile Oxides.

✍ Scribed by S. G. PYNE; J. SAFAEI-G.; B. W. SKELTON; A. H. WHITE

Book ID: 112025717
Publisher: John Wiley and Sons
Year: 2010
Weight: 37 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199604156

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The scope and limitations of dipolar cycloaddition reactions between nitrile oxides/nitrones and prop-1-ene-1,3-sultone have been investigated. A remarkably high degree of regioselectivity and stereoselectivity was observed. The homochiral sultam 8e was synthesized in a four-step reaction sequence s