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ChemInform Abstract: 1,3-Dipolar Cycloaddition Reaction of α,β-Unsaturated Esters and Lactones with Diazomethane.

✍ Scribed by S. BASKARAN; J. VASU; R. P. K. KODUKULLA; G. K. TRIVEDI; J. CHANDRASEKHAR


Book ID
112034363
Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
27
Category
Article
ISSN
0931-7597

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1,3-Dipolar cycloadditions of cyclic nit
✍ Pedro de March; Marta Figueredo; Josep Font; Antonio Salgado 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 630 KB

The 1,3-dipolar cycloaddition of cyclic nitrones to several "t-bromo ct,~unsaturated esters and lactones has been studied. All the reactions have shown high stereoselectivity, with a predominance of the endo or exo transition state for the trans or cis dipolarophiles, respectively.