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ChemInform Abstract: 1,3-Dioxolan-2-ylium Cations from Acylfurans: Conversion of Furyl Ketones to Esters under Nonoxidative Conditions.

✍ Scribed by J. A. BENDER; S. DAVES; F. G. WEST

Book ID: 101868741
Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199827054

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✦ Synopsis

1,3-Dioxolan-2-ylium Cations from Acylfurans: Conversion of Furyl Ketones to Esters under Nonoxidative Conditions. -Treatment of acylfurans (I) with 1,2-diols in the presence of an excess of TosOH yields glycol monoesters, probably via intermediate formation of 1,3-dioxolan-2-ylium cations. When the 1,3-diol (XI) is employed, furanoic acid ester (XII) is obtained. -(BENDER,

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