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ChemInform Abstract: 1,2-Hydrogen Shifts in Thermal and Photic Bamford—Stevens Reactions of Cyclohexanones. Activation by an Endocyclic Oxygen.

✍ Scribed by K. K. OLMSTEAD; A. NICKON


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


1,2-Hydrogen Shifts in Thermal and Photic Bamford-Stevens Reactions of Cyclohexanones. Activation by an Endocyclic Oxygen.

-The results of the Bamford-Stevens reaction of the steroid (I) found under thermal and photolytic conditions indicate that an endocyclic oxygen can activate 1,2-hydrogen shift more efficiently than an alkyl group. -(OLMSTEAD, K.