1,1,3,3,3-Pentafluoro-2-pentafluorophenylpropene oxide reacted with triethyl phosphite to give the ylide C 6 F 5 (CF 3 )Cβ«Χ‘β¬P(OEt) 3 . Hydrolysis yielded the phosphonate C 6 F 5 (CF 3 )CHP(O)(OEt) 2 , which was dehydrofluorinated using Et 3 N β’ BF 3 to form the vinyl phosphonate C 6 F 5 (CF 2 β«)Χ‘β¬CP
ChemInform Abstract: 1,1,3,3,3-Pentafluoro-2-pentafluorophenylpropene Oxide. Precursor for Novel Phosphonates and Ylides.
β Scribed by A. A. KADYROV; G.-V. ROESCHENTHALER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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