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ChemInform Abstract: 1-(Trifluoromethyl)-3,4-dihydropyrrolo[1,2-a]pyrazines (III): Synthesis and Reactions with O- and N-Nucleophiles.

โœ Scribed by V. I. Terenin; M. V. Galkin; E. V. Kabanova; A. S. Ivanov


Publisher
John Wiley and Sons
Year
2011
Weight
31 KB
Volume
42
Category
Article
ISSN
0931-7597

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Structure and Chemistry of 3,4-Dihydropyrrolo( 1,2-a)pyrazine. -The structure of title compound (I) and its N-protonated form is studied by ab initio calculations. The cyclic imino nitrogen can be quaternized to furnish azomethine ylide precursors which undergo inter-and intramolecular 1,3-dipolar