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ChemInform Abstract: 1-Acyl-4-benzylpyridinium Tetrafluoroborates: Stability, Structural Properties, and Utilization for the Synthesis of Acyl Fluorides.

โœ Scribed by Ruediger Wagner; Bernd Wiedel; Wolfgang Guenther; Helmar Goerls; Ernst Anders


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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1-Acyl-4-benzylpyridinium Tetrafluorobor
โœ Rรผdiger Wagner; Bernd Wiedel; Wolfgang Gรผnther; Helmar Gรถrls; Ernst Anders ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 226 KB ๐Ÿ‘ 2 views

Acyl-4-benzylpyridinium salts 4 containing nonnucleo-by the pyridine moiety of 4, which splits off and functions as a Lewis base to intercept the BF 3 acid. The structural and philic anions X -such as CF 3 SO 3 -, FSO 3 -, and BF 4 -can be generated quantitatively and in situ from 1-acyl-4-electroni