Chemiluminescence of Tricarbonyl(chloro)(1,10-phenanthroline)rhenium(I) during the Catalytic Decomposition of Tetralinyl Hydroperoxide

✍ Scribed by Prof. Dr. Arnd Vogler; Dr. Horst Kunkely

• Book ID: 101552127
• Publisher: John Wiley and Sons
• Year: 1981
• Tongue: English
• Weight: 215 KB
• Volume: 20
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198104691

✦ Synopsis

mixtures rearrange into 7-methyl-and 7-phenylcycloheptatriene, respectively, even at room temperature in CDC13, probably in a process catalyzed by traces of acid, whereas the exeisomers remain unchanged.

On reaction of ( I ) with tetrachlorodiazocyclopentadiene we did not observe a pyrazoline of type (2). Yellow crystals with m.p. 148°C are obtained in 11% yield, which we assign the fulvene structure (4) ['].