✦ LIBER ✦

Chemiluminescence of anthocyanins in the presence of acetaldehyde andtert-butyl hydroperoxide

✍ Scribed by Yoshiki, Yumiko ;Okubo, Kazuyoshi ;Igarashi, Kiharu

Publisher: John Wiley and Sons
Year: 1995
Weight: 299 KB
Volume: 10
Category: Article
ISSN: 0884-3996
DOI: 10.1002/bio.1170100605

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Light emission (chemiluminescence; CL) was observed in the reaction of anthocyanins with tert‐butyl hydroperoxide (t‐BuOOH) in the presence of acetaldehyde. The intensity of the CL of the anthocyanins was in the order of nasunin > rubrobrassicin > delphinidin > malvin = cyanidin > malvidin, indicating that glucosylation at C‐3 and C‐5 of the anthocyanin skeleton enhances the CL of the parent compound. CL intensity was enhanced at alkaline pH. The results suggest that the antioxidant effect of anthocyanins on lipid peroxidation, which is observed in the linoleic acid‐β‐carotene‐lipoxcygenase system, is at least partly due to their strong reactivity with hydroperoxides.

📜 SIMILAR VOLUMES

Colorimetric determination of acetaldehy

Colorimetric determination of acetaldehyde in the presence of formaldehyde

✍ Doron Dagani; Michael C. Archer 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 268 KB

Chemiluminescence of luminol in the pres

Chemiluminescence of luminol in the presence of hematin compounds

✍ Harold A. Neufeld; Charles J. Conklin; Richard D. Towner 📂 Article 📅 1965 🏛 Elsevier Science 🌐 English ⚖ 358 KB

Hydroxyalkylation of α-C—H Bonds of Tetr

Hydroxyalkylation of α-C—H Bonds of Tetrahydrofuran with Aldehydes in the Presence of Triethylborane and tert-Butyl Hydroperoxide.

✍ Takehiko Yoshimitsu; Yoshimasa Arano; Hiroto Nagaoka 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 18 KB

Improved Oxidation of Active Methyl Grou

Improved Oxidation of Active Methyl Group of N-Heteroaromatic Compounds by Selenium Dioxide in the Presence of tert-Butyl Hydroperoxide.

✍ Yoshinobu Tagawa; Katsuya Yamashita; Yoshitaka Higuchi; Yoshinobu Goto 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 97 KB 👁 2 views

## Abstract For Abstract see ChemInform Abstract in Full Text.

Homopolymerization of Butyl Acrylate in

Homopolymerization of Butyl Acrylate in the Presence of Dodecanethiol

✍ José Luis de la Fuente; Enrique López Madruga 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 184 KB 👁 1 views

ln of the rate of polymerization vs [DDT]/[BA] for homopolymerization of butyl acrylate at 40, 50 and 60 8C, in a 3 mol/ L benzene solution and with [AIBN] = 5 6 10 -3 mol/L.

Kinetics of Cyclooctene Epoxidation with

Kinetics of Cyclooctene Epoxidation with tert-Butyl Hydroperoxide in the Presence of [MoO2X2L]-Type Catalysts (L = Bidentate Lewis Base)

✍ Ahmad Al-Ajlouni; Anabela A. Valente; Carla D. Nunes; Martyn Pillinger; Ana M. S 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB 👁 1 views