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Chemiluminescence in the decomposition of di(tert-butyl) trioxide (CH3)3C-OOO-C(CH3)3

✍ Scribed by A. F. Khalizov; S. L. Khursan; V. V. Shereshovets; V. D. Komissarov

Book ID
112387429
Publisher
Springer
Year
1993
Tongue
English
Weight
153 KB
Volume
42
Category
Article
ISSN
1573-9171

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✍ Lászloó Seres; Ágnes Nacsa; Neville L. Arthur 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 1024 KB

A study of the reaction initiated by the thermal decomposition of di-t-butyl peroxide (DTBP) in the presence of (CHa)?C=CHz (B) at 391-444 K has yielded kinetic data on a number of reactions involving CH3 (M.), (CH&CCHzCH3 (MB.) and ( C H ~) ~C C H ~C ( C H ~) Z C H ~C H ~ (MBB.) radicals. The cross