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Chemical synthesis of a dextran model, poly-α-(1 → 6)-anhydro-D-glucopyranose

✍ Scribed by Erwin R. Ruckel; Conrad Schuerch

Publisher: Wiley (John Wiley & Sons)
Year: 1967
Tongue: English
Weight: 500 KB
Volume: 5
Category: Article
ISSN: 0006-3525
DOI: 10.1002/bip.1967.360050606

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✦ Synopsis

Poly-u-( 1 + 6)-anhydro-~-glucopyrariose has been synthesized by the phosphoriis pentaflnoride-catalyzed polymerization of 1,&-anhydro-2,3,4-tri-O-benzyI-~-~-gl~icopyranose and subsequent debenzylation. Physical characterization establishes its high polymeric character and stereoregdarity.

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