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Chemical Structure and Biochemical Activity of Cord Factor Analogs : 6,6′-Dimycoloyl Sucrose and Methyl 6-Mycoloyl-α-d-glucoside

✍ Scribed by Masahiko Kato; Jean Asselineau


Book ID
115112847
Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
548 KB
Volume
22
Category
Article
ISSN
1432-1327

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Cord-factor analogs: synthesis of 6,6′-d
✍ Avraham Liav; Harold M. Flowers; Mayer B. Goren 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 445 KB

Appropriate solvolysis of 2,3,2',3'-tetra-O-benzyl-4,6,4',6'-tetra-O-mesyla,a-trehalose gave 2,3,2',3'-tetra-O-benzyl-(a-D-galactopyranosyl a-D-galactopyranoside) (2). Selective tosylation or mesylation of 2 respectively gave the 6,6'ditosylate (3) and 6,6'-dimesylate (4), the structures of which we