Chemical source of singlet oxygen, or its synthetic equivalent. Generation from resin-bound peroxomolybdate
✍ Scribed by Ernest C McGoran; Mark Wyborney
- Book ID
- 104233055
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 307 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Singlet oxygen, or its synthetic equivalent, is generated by the action of resin-bound molybdate on hydrogen peroxide. Resin-bound peroxomolybdate converts reactant olefins to their ene, [4+2] and [2+2] cyctoaddition or secondary products.
Over the past several years singlet oxygen, 102, has emerged as a powerful synthetic reagent for the introduction of the peroxide function or its supersedents with a remarkable degree of regioselectivityl ~ This reagent has evoked more recent interest because it can provide explicit routes to analogs of naturally occurring peroxides*, many reported to possess potent biological3 or pharmacologic properlies4.